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Tris[N,N-bis(trimethylsilyl)amide]cerium(III), 98%, Thermo Scientific Chemicals

1040.00 NOK - 26830.00 NOK

Chemical Identifiers

CAS 41836-21-9
Molecular Formula C18H54CeN3Si6
Molecular Weight (g/mol) 621.277
MDL Number MFCD03411241
InChI Key DPCZDYUESIKMSU-UHFFFAOYSA-N
Synonym bis trimethylsilyl azanide; cerium 3+, tris bis trimethylsilyl amino cerium iii, cerium 3+ tris bis trimethylsilyl azanide, tris n,n-bis trimethylsilyl amide cerium iii , 96 %
PubChem CID 6093781
IUPAC Name bis(trimethylsilyl)azanide;cerium(3+)
SMILES C[Si](C)(C)[N-][Si](C)(C)C.C[Si](C)(C)[N-][Si](C)(C)C.C[Si](C)(C)[N-][Si](C)(C)C.[Ce+3]
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11488520
SDS View Documents
Thermo Scientific Alfa Aesar
044362.03
1 g This item is currently unavailable or has been discontinued.
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N/A
11478520
SDS View Documents
Thermo Scientific Alfa Aesar
044362.06
5 g This item is currently unavailable or has been discontinued.
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N/A
11400710
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Thermo Scientific Alfa Aesar
044362.14
25 g This item is currently unavailable or has been discontinued.
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N/A
Description

Description

Tris[N,N-bis(trimethylsilyl)amide]cerium(III) is used as a reactant for synthesis of amidocerium(IV) oxides, Sterically encumbered N-heterocyclic carbene ligands, Lanthanide imidodiphosphinate complexes with electroluminescent properties, Lanthanide complexes of an oxazoline-phenoxide hybrid chelate. Some of the other applications include it is used as a reactant for One-electron oxidation to produce tetravalent cerium compounds, Addition-elimination reactions across the M-C bond of metal N-heterocyclic carbenes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

41836-21-9
621.277
DPCZDYUESIKMSU-UHFFFAOYSA-N
6093781
C[Si](C)(C)[N-][Si](C)(C)C.C[Si](C)(C)[N-][Si](C)(C)C.C[Si](C)(C)[N-][Si](C)(C)C.[Ce+3]
C18H54CeN3Si6
MFCD03411241
bis trimethylsilyl azanide; cerium 3+, tris bis trimethylsilyl amino cerium iii, cerium 3+ tris bis trimethylsilyl azanide, tris n,n-bis trimethylsilyl amide cerium iii , 96 %
bis(trimethylsilyl)azanide;cerium(3+)

Specifications

41836-21-9
C18H54CeN3Si6
MFCD03411241
Moisture Sensitive
DPCZDYUESIKMSU-UHFFFAOYSA-N
bis(trimethylsilyl)azanide;cerium(3+)
6093781
98%
Tris[N,N-bis (trimethylsilyl)amide]cerium (III)
Yellow
[[(CH3)3Si]2N]3Ce
UN3396
bis trimethylsilyl azanide; cerium 3+, tris bis trimethylsilyl amino cerium iii, cerium 3+ tris bis trimethylsilyl azanide, tris n,n-bis trimethylsilyl amide cerium iii , 96 %
C[Si](C)(C)[N-][Si](C)(C)C.C[Si](C)(C)[N-][Si](C)(C)C.C[Si](C)(C)[N-][Si](C)(C)C.[Ce+3]
621.277
621.27
Powder
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Safety and Handling

Safety and Handling

GHS H Statement
H261-H228-H314-H318
In contact with water releases flammable gas.
Flammable solid.
Causes severe skin burns and eye damage.
Causes serious eye damage.

GHS P Statement
P210-P280-P305+P351+P338-P309-P310-P402+P404
Keep away from heat/sparks/open flames/hot surfaces.
- No smoking.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.
Store in a dry place.
Store in a closed container.

Danger

missing translation for 'dotInformation' : Transport Hazard Class: 4.3; Packing Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE, FLAMMABLE

SDS
Documents

Documents

Product Certifications

RUO – Research Use Only

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