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tert-Butyldichlorophosphine, 98%, Thermo Scientific Chemicals
CAS: 25979-07-1 | C4H9Cl2P | 158.99 g/mol
528.00 NOK - 7765.00 NOK
Chemical Identifiers
| CAS | 25979-07-1 |
|---|---|
| Molecular Formula | C4H9Cl2P |
| Molecular Weight (g/mol) | 158.99 |
| MDL Number | MFCD00013615 |
| InChI Key | NMJASRUOIRRDSX-UHFFFAOYSA-N |
| Synonym | tert-butyldichlorophosphine, t-butyldichlorophosphine, tert-c4h9pcl2, tert-butyl dichloro phosphane, phosphonous dichloride, 1,1-dimethylethyl, snpladsptpdwuup@, pubchem6471, acmc-1cmec, tert-butyl dichloro phosphine, tert-butylphosphine dichloride |
| PubChem CID | 117690 |
| IUPAC Name | tert-butyl(dichloro)phosphane |
| SMILES | CC(C)(C)P(Cl)Cl |
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|---|---|---|---|---|---|---|---|---|---|
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|
11317129
|
Thermo Scientific Alfa Aesar
H27360.03 |
1 g | N/A | ||||||
|
11327129
|
Thermo Scientific Alfa Aesar
H27360.09 |
10 g | N/A | ||||||
|
11337129
|
Thermo Scientific Alfa Aesar
H27360.18 |
50 g |
7765.00 NOK
50g |
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Description
Reactant for the synthesis of alkali metal complexes. As intermediates. tert-Butyldichlorophosphine (TBDCP) is used primarily in the preparation of monoand bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsReactant for the synthesis of alkali metal complexes. As intermediates. tert-Butyldichlorophosphine (TBDCP) is used primarily in the preparation of monoand bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.
Solubility
Reacts with water. Soluble in n-Pentane, n-Hexane, Ether, Toluene,THF. tert-Butyldichlorophosphine is infinitely soluble in hydrocarbon and ethereal solvents.
Notes
Air & Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, strong bases, air, water and moisture.
Chemical Identifiers
| 25979-07-1 | |
| 158.99 | |
| NMJASRUOIRRDSX-UHFFFAOYSA-N | |
| 117690 | |
| CC(C)(C)P(Cl)Cl |
| C4H9Cl2P | |
| MFCD00013615 | |
| tert-butyldichlorophosphine, t-butyldichlorophosphine, tert-c4h9pcl2, tert-butyl dichloro phosphane, phosphonous dichloride, 1,1-dimethylethyl, snpladsptpdwuup@, pubchem6471, acmc-1cmec, tert-butyl dichloro phosphine, tert-butylphosphine dichloride | |
| tert-butyl(dichloro)phosphane |
Specifications
| 25979-07-1 | |
| C4H9Cl2P | |
| MFCD00013615 | |
| Air and moisture sensitive | |
| Reacts with water. Soluble in n-Pentane,n-Hexane,Ether,Toluene,THF. tert-Butyldichlorophosphine is infinitely soluble in hydrocarbon and ethereal solvents. | |
| CC(C)(C)P(Cl)Cl | |
| 158.99 | |
| 159 | |
| tert-Butyldichlorophosphine |
| 44°C to 49°C | |
| (CH3)3CPCl2 | |
| UN3261 | |
| tert-butyldichlorophosphine, t-butyldichlorophosphine, tert-c4h9pcl2, tert-butyl dichloro phosphane, phosphonous dichloride, 1,1-dimethylethyl, snpladsptpdwuup@, pubchem6471, acmc-1cmec, tert-butyl dichloro phosphine, tert-butylphosphine dichloride | |
| NMJASRUOIRRDSX-UHFFFAOYSA-N | |
| tert-butyl(dichloro)phosphane | |
| 117690 | |
| 98% |
Safety and Handling
GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.
P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
H314-H335
missing translation for 'dotInformation' : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
missing translation for 'einecsNumber' : 247-386-9
missing translation for 'tsca' : No
Recommended Storage : Ambient temperatures; Store under Nitrogen
RUO – Research Use Only
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