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Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II), Thermo Scientific Chemicals
CAS: 15629-92-2 | C27H26Cl2NiP2 | 542.04 g/mol
779.00 NOK - 2555.00 NOK
Chemical Identifiers
| CAS | 15629-92-2 |
|---|---|
| Molecular Formula | C27H26Cl2NiP2 |
| Molecular Weight (g/mol) | 542.04 |
| MDL Number | MFCD00015318 |
| InChI Key | REQVOKPBMSCTNI-UHFFFAOYSA-L |
| Synonym | 1,3-Bis(diphenylphosphino)propane nickel(II) chloride |
| PubChem CID | 131675641 |
| IUPAC Name | 3-diphenylphosphanylpropyl(diphenyl)phosphane;nickel;dihydrochloride |
| SMILES | Cl[Ni++]Cl.C(CP(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1 |
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|---|---|---|---|---|---|---|---|---|---|
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|
11317238
|
Thermo Scientific Alfa Aesar
030167.04 |
2 g |
779.00 NOK
2g |
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|
11307238
|
Thermo Scientific Alfa Aesar
030167.09 |
10 g |
2555.00 NOK
10g |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
Description
Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Chemical Identifiers
| 15629-92-2 | |
| 542.04 | |
| REQVOKPBMSCTNI-UHFFFAOYSA-L | |
| 131675641 | |
| Cl[Ni++]Cl.C(CP(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1 |
| C27H26Cl2NiP2 | |
| MFCD00015318 | |
| 1,3-Bis(diphenylphosphino)propane nickel(II) chloride | |
| 3-diphenylphosphanylpropyl(diphenyl)phosphane;nickel;dihydrochloride |
Specifications
| 15629-92-2 | |
| C27H26Cl2NiP2 | |
| 1,3-Bis(diphenylphosphino)propane nickel(II) chloride | |
| REQVOKPBMSCTNI-UHFFFAOYSA-L | |
| 3-diphenylphosphanylpropyl(diphenyl)phosphane;nickel;dihydrochloride | |
| 131675641 | |
| Powder |
| 213°C (decomposition) | |
| MFCD00015318 | |
| Insoluble in water. | |
| Cl[Ni++]Cl.C(CP(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1 | |
| 542.04 | |
| 542.03 | |
| Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) |
Safety and Handling
GHS H Statement
H351-H315-H319-H317-H335
Suspected of causing cancer.
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
May cause respiratory irritation.
P201-P202-P261-P264b-P271-P272-P280-P281-P285-P302+P352-P304+P340-P305+P351+P338-P308+P313-P333+P313-P342+P311-P362-P501c
H315-H317-H319-H334-H335-H350
missing translation for 'tsca' : No
Recommended Storage : Ambient temperatures
Product Identifier
Signal Word
Hazard Category
Hazard Statement
Precautionary Statement
- Dichloro¢bis(1,3-diphenylphosphino)propane!nickel(II)
Signal Word
- Danger
Hazard Category
- Skin corrosion/irritation Category 2
- Serious eye damage/eye irritation Category 2
- Skin sensitiser Category 1
- Carcinogenicity Category 2
- Specific target organ toxicity Category 3
Hazard Statement
- H315-Causes skin irritation.
- H319-Causes serious eye irritation.
- H317-May cause an allergic skin reaction.
- H351-Suspected of causing cancer.
- H335-May cause respiratory irritation.
Precautionary Statement
- P201-Obtain special instructions before use.
- P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
- P280-Wear protective gloves/protective clothing/eye protection/face protection.
- P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P312-Call a POISON CENTER/doctor/if you feel unwell.
- P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P308+P313-IF exposed or concerned: Get medical advice/attention.
- P405-Store locked up.
- P403+P233-Store in a well-ventilated place. Keep container tightly closed.
- P501-Dispose of contents/container to .
RUO – Research Use Only
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