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1-Bromo-3-methyl-2-butene, 90+%, stab. with silver
Description
1-Bromo-3-methyl-2-butene is considered as a source of 3,3-dimethylallyl group and used in the preparation of natural products. It is also employed in the synthesis of base-modified pyrimidine nucleosides. Further, it is used in the preparation of (±)-eldanolide, 1-(3,3-dimethylallyl)-L-tryptophan and (±)-fumagillin, an antibiotic isolated from Aspergillus fumigattus.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
1-Bromo-3-methyl-2-butene is considered as a source of 3,3-dimethylallyl group and used in the preparation of natural products. It is also employed in the synthesis of base-modified pyrimidine nucleosides. Further, it is used in the preparation of (±)-eldanolide, 1-(3,3-dimethylallyl)-L-tryptophan and (±)-fumagillin, an antibiotic isolated from Aspergillus fumigattus.
Solubility
Immiscible with water
Notes
Store in a cool place. Incompatible with strong oxidizing agents and strong bases
Specifications
Specifications
| Density | 1.281 |
| Boiling Point | 135°C |
| Flash Point | 32°C (90°F) |
| Odor | Pungent |
| Refractive Index | 1.4895 |
| Quantity | 50 g |
| UN Number | UN2920 |
| Beilstein | 1420778 |
| Sensitivity | Light sensitive |
| Solubility Information | Immiscible with water |
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Safety and Handling
- 1-Bromo-3-methyl-2-butene
- Danger
- Serious eye damage/eye irritation Category 1
- Flammable liquid Category 3
- Skin corrosion/irritation Category 1 B
- H226-Flammable liquid and vapour.
- H314-Causes severe skin burns and eye damage.
- H318-Causes serious eye damage.
- P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
- P280-Wear protective gloves/protective clothing/eye protection/face protection.
- P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
- P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P310-Immediately call a POISON CENTER/doctor/.
- MIXTURE LIST-Contains : 1-Bromo-3-methyl-2-butene
RUO – Research Use Only
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